From
 http://www.mysite.com/admin
To
 http://www.mysite.com/sitemanager

1) Open app/etc/local.xml
2) Find this code:

 <config>
.
.
<admin>
<routers>
<adminhtml>
<args>
<frontName><![CDATA[admin]]></frontName>
</args>
</adminhtml>
</routers>
</admin>
.
.
</config> 

3) In that code, change

 <frontName><![CDATA[admin]]></frontName> 

to

 <frontName><![CDATA[sitemanager]]></frontName> 

4) Save the local.xml file

5) Remove everything under var/cache/
6) Remove everything under var/session/

Then try the url….

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